I had been checking the graphic setting originally though the Falloutlauncher via steam(Opps), I just used MO to open the FalloutLauncher executable and was shown the same settings I saw in steam. Besides the FalloutLauncher all other executable have been ran through Mod Organizer. The settings appear to be wrongly set only when launching the 4gb loader through MO. When using MO to launch any other executable everything works properly. I just tried what you suggested, running the Fallout Launcher through MO, and everything appeared to be in order with the graphic settings. Afterwards, I ran the 4gb Loader again, through MO, and the settings where still not loading.